English

Efficient, long-range correlation from occupied wavefunctions only

Mesoscale and Nanoscale Physics 2012-08-28 v4 Atomic Physics

Abstract

We use continuum mechanics [Tao \emph{et al}, PRL{\bf 103},086401] to approximate the dynamic density response of interacting many-electron systems. Thence we develop a numerically efficient exchange-correlation energy functional based on the Random Phase Approximation (dRPA). The resulting binding energy curve E(D)E(D) for thin parallel metal slabs at separation DD better agrees with full dRPA calculations than does the Local Density Approximation. We also reproduce the correct non-retarded van der Waals (vdW) power law E(D)\aeqC5/2D5/2E(D)\aeq -C_{5/2}D^{-5/2} as DD\to\infty, unlike most vdW functionals.

Keywords

Cite

@article{arxiv.1106.0327,
  title  = {Efficient, long-range correlation from occupied wavefunctions only},
  author = {Tim Gould and John F. Dobson},
  journal= {arXiv preprint arXiv:1106.0327},
  year   = {2012}
}

Comments

4 pages, 1 figure

R2 v1 2026-06-21T18:16:28.186Z