English

Efficiency at maximum power of a chemical engine

Chemical Physics 2015-06-16 v2 Statistical Mechanics

Abstract

A cyclically operating chemical engine is considered that converts chemical energy into mechanical work. The working fluid is a gas of finite-sized spherical particles interacting through elastic hard collisions. For a generic transport law for particle uptake and release, the efficiency at maximum power η\eta takes the form 1/2+c\Delta \mu + O(\Delta \mu^2), with 1/2 a universal constant and Δμ\Delta \mu the chemical potential difference between the particle reservoirs. The linear coefficient c is zero for engines featuring a so-called left/right symmetry or particle fluxes that are antisymmetric in the applied chemical potential difference. Remarkably, the leading constant in η\eta is non-universal with respect to an exceptional modification of the transport law. For a nonlinear transport model we obtain \eta = 1/(\theta +1), with \theta >0 the power of Δμ\Delta \mu in the transport equation

Keywords

Cite

@article{arxiv.1306.3866,
  title  = {Efficiency at maximum power of a chemical engine},
  author = {Hans Hooyberghs and Bart Cleuren and Alberto Salazar and Joseph O. Indekeu and Christian Van den Broeck},
  journal= {arXiv preprint arXiv:1306.3866},
  year   = {2015}
}
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