Effective Perrin theory for the anisotropic diffusion of a strongly hindered rod
Soft Condensed Matter
2009-02-02 v2
Abstract
Slender rods in concentrated suspensions constitute strongly interacting systems with rich dynamics: transport slows down drastically and the anisotropy of the motion becomes arbitrarily large. We develop a mesoscopic description of the dynamics down to the length scale of the interparticle distance. Our theory is based on the exact solution of the Smoluchowski-Perrin equation; it is in quantitative agreement with extensive Brownian dynamics simulations in the dense regime. In particular, we show that the tube confinement is characterised by a power law decay of the intermediate scattering function with exponent 1/2.
Keywords
Cite
@article{arxiv.0808.0450,
title = {Effective Perrin theory for the anisotropic diffusion of a strongly hindered rod},
author = {Tobias Munk and Felix Höfling and Erwin Frey and Thomas Franosch},
journal= {arXiv preprint arXiv:0808.0450},
year = {2009}
}
Comments
to appear in EPL