English

Effect of grafting on the binding transition of two flexible polymers

Soft Condensed Matter 2017-04-07 v1 Statistical Mechanics

Abstract

We investigate the binding transition of two flexible polymers grafted to a steric surface with closeby end points. While free polymers show a discontinuous transition, grafting to a steric flat surface leads to a continuous binding transition. This is supported by results from Metropolis and parallel multicanonical simulations. A combination of canonical and microcanonical analyses reveals that the change in transition order can be understood in terms of the reduced translational entropy of the unbound high-temperature phase upon grafting.

Keywords

Cite

@article{arxiv.1612.01778,
  title  = {Effect of grafting on the binding transition of two flexible polymers},
  author = {Johannes Zierenberg and Katharina Tholen and Wolfhard Janke},
  journal= {arXiv preprint arXiv:1612.01778},
  year   = {2017}
}

Comments

10 pages, 6 figures, submitted to Eur. Phys. J Spec. Topics