English

Dynamical scaling for underdamped strain order parameters quenched below first-order phase transitions

Statistical Mechanics 2016-12-07 v1 Materials Science

Abstract

In the conceptual framework of phase ordering after temperature quenches below transition, we consider the underdamped Bales-Gooding-type 'momentum conserving' dynamics of a 2D martensitic structural transition from a square-to-rectangle unit cell. The one-component or NOP=1N_{\rm OP} =1 order parameter is one of the physical strains, and the Landau free energy has a triple well, describing a first-order transition. We numerically study the evolution of the strain-strain correlation, and find that it exhibits dynamical scaling, with a coarsening length L(t)tαL(t) \sim t^{\alpha}. We find at intermediate and long times that the coarsening exponent sequentially takes on respective values close to α=2/3\alpha=2/3 and α=1/2\alpha=1/2. For deep quenches, the coarsening can be arrested at long times, with α0\alpha \simeq 0. These exponents are also found in 3D. To understand such behaviour, we insert a dynamical-scaling ansatz into the correlation function dynamics to give, at a dominant scaled separation, a nonlinear kinetics of the curvature g(t)1/L(t)g (t) \equiv 1/ L(t). The curvature solutions have time windows of power-law decays g1/tαg \sim 1/t^\alpha, with exponent values α\alpha matching simulations, and manifestly independent of spatial dimension. Applying this curvature-kinetics method to mass-conserving Cahn-Hilliard dynamics for a double-well Landau potential in a scalar NOP=1N_{\rm OP}=1 order parameter yields exponents α=1/4\alpha = 1/4 and 1/31/3 for intermediate and long times. For vector order parameters with NOP2N_{\rm OP} \geq 2, the exponents are α=1/4\alpha = 1/4 only, consistent with previous work. The curvature kinetics method could be useful in extracting coarsening exponents for other phase-ordering dynamics.

Keywords

Cite

@article{arxiv.1612.01737,
  title  = {Dynamical scaling for underdamped strain order parameters quenched below first-order phase transitions},
  author = {N. Shankaraiah and Awadhesh K. Dubey and Sanjay Puri and Subodh R. Shenoy},
  journal= {arXiv preprint arXiv:1612.01737},
  year   = {2016}
}

Comments

18 pages, 16 figures

R2 v1 2026-06-22T17:14:36.876Z