Diode Effect May Assist Finding Proper Superconductivity Mechanism in Copper Oxides

We present measurements demonstrating that copper-oxide high-temperature superconductors can exhibit broken time-reversal symmetry in the absence of external magnetic fields. Using $Tl_{2}Ba_{2}CaCu_{2}O_{8}$ microbridges, we observe a pronounced superconducting diode effect at 100 K under strictly zero-field conditions. This nonreciprocal response remains unchanged in magnetic fields up to $\pm 100 Oe$. Our results are consistent with recent reports of zero-field diode behavior in $Bi_{2}Sr_{2}CaCu_{2}O_{8+{\delta} }$ and together indicate that time-reversal symmetry breaking may be an intrinsic property of the cuprate superconducting state. These findings significantly constrain theoretical models of high-temperature superconductivity that rely on time-reversal-symmetric mechanisms.