English

Diffusion in a generalized Rubinstein-Duke model of electrophoresis with kinematic disorder

Soft Condensed Matter 2009-11-10 v1

Abstract

Using a generalized Rubinstein-Duke model we prove rigorously that kinematic disorder leaves the prediction of standard reptation theory for the scaling of the diffusion constant in the limit for long polymer chains DL2D \propto L^{-2} unaffected. Based on an analytical calculation as well as Monte Carlo simulations we predict kinematic disorder to affect the center of mass diffusion constant of an entangled polymer in the limit for long chains by the same factor as single particle diffusion in a random barrier model.

Keywords

Cite

@article{arxiv.cond-mat/0301348,
  title  = {Diffusion in a generalized Rubinstein-Duke model of electrophoresis with kinematic disorder},
  author = {R. D. Willmann and G. M. Schütz and K. Jain},
  journal= {arXiv preprint arXiv:cond-mat/0301348},
  year   = {2009}
}

Comments

29 pages, 3 figures, submitted to PRE