English

Density scaling as a property of strongly correlating viscous liquids

Soft Condensed Matter 2012-03-27 v2 Disordered Systems and Neural Networks

Abstract

We address a recent conjecture according to which the relaxation time τ\tau of a viscous liquid obeys density scaling (τ=F(ργ/T)\tau=F(\rho^\gamma/T) where ρ\rho is density) if the liquid is ``strongly correlating,'' i.e., has almost 100% correlation between equilibrium virial and potential-energy fluctuations [Pedersen {\it et al.}, PRL {\bf 100}, 011201 (2008)]. Computer simulations of two model liquids - an asymmetric dumbbell model and the Lewis-Wahnstr\"om OTP model - confirm the conjecture and demonstrate that the scaling exponent γ\gamma can be accurately predicted from equilibrium fluctuations.

Keywords

Cite

@article{arxiv.0803.2199,
  title  = {Density scaling as a property of strongly correlating viscous liquids},
  author = {Thomas B. Schrøder and Ulf R. Pedersen and Jeppe C. Dyre},
  journal= {arXiv preprint arXiv:0803.2199},
  year   = {2012}
}

Comments

5 pages, 5 figures. Data added for Lewis-Wahnstrom OTP