Density scaling as a property of strongly correlating viscous liquids
Soft Condensed Matter
2012-03-27 v2 Disordered Systems and Neural Networks
Abstract
We address a recent conjecture according to which the relaxation time of a viscous liquid obeys density scaling ( where is density) if the liquid is ``strongly correlating,'' i.e., has almost 100% correlation between equilibrium virial and potential-energy fluctuations [Pedersen {\it et al.}, PRL {\bf 100}, 011201 (2008)]. Computer simulations of two model liquids - an asymmetric dumbbell model and the Lewis-Wahnstr\"om OTP model - confirm the conjecture and demonstrate that the scaling exponent can be accurately predicted from equilibrium fluctuations.
Keywords
Cite
@article{arxiv.0803.2199,
title = {Density scaling as a property of strongly correlating viscous liquids},
author = {Thomas B. Schrøder and Ulf R. Pedersen and Jeppe C. Dyre},
journal= {arXiv preprint arXiv:0803.2199},
year = {2012}
}
Comments
5 pages, 5 figures. Data added for Lewis-Wahnstrom OTP