Density induced BCS-Bose evolution in gated two-dimensional superconductors: The Berezinskii-Kosterlitz-Thouless transition as a function of carrier density

We discuss the evolution from BCS to Bose superconductivity versus carrier density in gated two-dimensional s-wave superconductors. We show that the transition from the normal to the superconducting state is controlled by the Berezinskii-Kosterlitz-Thouless vortex-antivortex pairing mechanism, and that the evolution from high carrier density (BCS pairing) to low carrier density (Bose pairing) is just a crossover in s-wave systems. We compare our results to recent experiments on the superconductor LixZrNCl, a lithium intercalated layered nitride, and obtain very good quantitative agreement at low and intermediate densities.