English

Crystal structure and low-energy Einstein mode in ErV$_2$Al$_{20}$ intermetallic cage compound

Materials Science 2016-10-11 v1

Abstract

Single crystals of a new ternary aluminide ErV2_2Al20_{20} were grown using a self-flux method. The crystal structure was determined by powder X-ray diffraction measurements and Rietveld refinement, and physical properties were studied by means of electrical resistivity, magnetic susceptibility and specific heat measurements. These measurements reveal that ErV2_2Al20_{20} is a Curie-Weiss paramagnet down to 1.95 K with an effective magnetic moment μeff\mu_{eff} = 9.27(1) μB\mu_B and Curie-Weiss temperature ΘCW\Theta_{CW} = -0.55(4) K. The heat capacity measurements show a broad anomaly at low temperatures that is attributed to the presence of a low-energy Einstein mode with characteristic temperature ΘE\Theta_E = 44 K, approximately twice as high as in the isostructural 'Einstein solid' VAl10.1_{10.1}.

Keywords

Cite

@article{arxiv.1609.07161,
  title  = {Crystal structure and low-energy Einstein mode in ErV$_2$Al$_{20}$ intermetallic cage compound},
  author = {Michał J. Winiarski and Tomasz Klimczuk},
  journal= {arXiv preprint arXiv:1609.07161},
  year   = {2016}
}

Comments

15 pages, 9 figures + Supplementary Material; Accepted for publication in Journal of Solid State Chemistry

R2 v1 2026-06-22T15:58:36.283Z