The solution to the long standing problem of the cohesion of organic chain compounds is proposed. We consider the tight-binding dielectric matrix with two electronic bands per chain, determine the corresponding hybridized collective modes, and show that three among them are considerably softened due to strong dipole-dipole and monopole-dipole interactions. By this we explain the unusual low frequency optical activity of TTF-TCNQ, including the observed 10meV anomaly. The softening of the modes also explains the cohesion of the mixed-stack lattice, the fractional charge transfer almost independent of the material, and the formation of the charged sheets in some compounds.
@article{arxiv.cond-mat/9812194,
title = {Crystal stability and optical properties of organic chain compounds},
author = {P. Zupanovic and A. Bjelis and S. Barisic},
journal= {arXiv preprint arXiv:cond-mat/9812194},
year = {2009}
}
Comments
7 pages, 1 figure, to be published in Europhysics Letters