Creation of Lunar-Like Rims in Ilmenite using Synthetic Solar Wind

Space weathering of lunar minerals, due to bombardment from solar wind (SW) particles and micrometeoroid impacts, modifies the mineralogy within tens of nanometers of the surface, i.e., the rim. Via remote sensing, spectroscopic signatures of these modifications have long been used to gauge surface exposure times on the Moon. However, the relative contributions of solar wind and micrometeoroids in the creation of rim features are still debated, particularly for the few-nm clusters known as nanophase iron (npFe0), which commonly form in ferrous minerals. We address this issue in the laboratory, using deuterium ions and low-energy electrons as a synthetic solar wind plasma to irradiate ilmenite (FeTiO3), a common lunar mineral. Characterization by high-resolution scanning transmission electron microscopy and electron energy-loss spectroscopy shows that the solar wind alone creates rims with all the main characteristics of lunar samples. We conclusively identify npFe0 and quantify its distribution as a function of depth and fluence, allowing us to estimate the SW exposure of Apollo soil 71501. Our results confirm that small npFe0 (<10 nm in diameter) form due to the solar wind. Similar experiments could provide microscopic details of space weathering, improving the link between surface modification processes and macroscopic remote sensing data.