Contactium: A strongly correlated model system
Abstract
At the limit of an infinite confinement strength , the ground state of a system that comprises two fermions or bosons in a harmonic confinement interacting through the Fermi--Huang pseudopotential remains strongly correlated. A detailed analysis of the one-particle description of this ``contactium'' reveals several peculiarities that are not encountered in conventional model systems (such as the two-electron harmonium atom, ballium, and spherium) involving Coulombic interparticle interactions. First of all, none of the natural orbitals (NOs) of the contactium is unoccupied, which implies nonzero collective occupancies for all the angular momenta. Second, the NOs and their nonascendingly ordered occupation numbers turn out to be related to the eigenfunctions and eigenvalues of a zero-energy Schr\"odinger equation with an attractive Gaussian potential. This observation enables the derivation of their properties such as the asymptotic decay of at the limit (which differs from that of in the Coulombic systems), the independence of the confinement energy {v_\mathfrak{n} = \langle \psi_\mathfrak{n}(\omega;\vec r) | \frac{1}{2} % \omega^2r^2 | \psi_\mathfrak{n}(\omega;\vec r) \rangle} of , and the asymptotic decay of the respective contribution to the kinetic energy. Upon suitable scaling, the weakly occupied NOs of the contactium turn out to be virtually identical with those of the two-electron harmonium atom at the limit, despite the entirely different interparticle interactions in these systems.
Cite
@article{arxiv.2303.14982,
title = {Contactium: A strongly correlated model system},
author = {Jerzy Cioslowski and Berthold-Georg Englert and Martin-Isbjörn Trappe and Jun Hao Hue},
journal= {arXiv preprint arXiv:2303.14982},
year = {2023}
}
Comments
9 pages, 5 figures, 1 table