English

Constructive Quantum Interference in a Photo-Chemical Reaction of $^{87}$Rb Bose Einstein Condensate

Quantum Physics 2021-07-13 v1

Abstract

Interferences emerge when multiple pathways coexist together leading towards the same result. A Recent study by Blasing and coworkers [PRL 121(7):073202] showed that in a photo-association reaction of Raman dressed spin orbit coupled 87^{87}Rb Bose Einstein Condensate when the reactant spin state is prepared in a coherent superposition of multiple bare spin states it leads to a destructive interference between reaction pathways. Here we report a theoretical study for a reaction scheme which leads to constructive quantum interference. This is achieved by changing the reactive scattering channel in the reaction. As the origin of coherent control comes from the spin part of the wavefunction it is sufficient to use radio frequency coupling to achieve the superposition state. Our results show that interferences can be used as a resource for the coherent control of photo-chemical reactions. The approach is general and can be employed to study a wide spectra of chemical reactions in the ultracold regime.

Keywords

Cite

@article{arxiv.2107.05441,
  title  = {Constructive Quantum Interference in a Photo-Chemical Reaction of $^{87}$Rb Bose Einstein Condensate},
  author = {Sumit Suresh Kale and Yong P. Chen and Sabre Kais},
  journal= {arXiv preprint arXiv:2107.05441},
  year   = {2021}
}