Comparative qualification of advanced plasma-facing materials for fusion pilot plants through public- and private-sector experiments in DIII-D

A coordinated DIII-D campaign exposed and comparatively assessed 44 advanced plasma-facing materials from 12 institutions, including four public-private fusion partnerships, to support fusion pilot plant wall and divertor material down-selection. Samples were exposed using the Divertor Materials Evaluation System (DiMES) under Ohmic, L-mode, and H-mode conditions with edge-localized modes, at 0.2-2.5 MW m$^{-2}$ on flush geometries and 10-15 MW m$^{-2}$ on 10$^{\circ}$ angled geometries. Engineered tungsten architectures retained integrity; long-fiber Wf/W showed the clearest crack-arrest behavior. W-Re and K-doped W showed near-ITER-W-like responses, while additively manufactured W-Ta showed heat-flux-sensitive mass losses of 0.64 mg for the flat sample and 2.19-2.87 mg for angled samples. After irradiation to 0.3 dpa at 550$^{\circ}$C, neutron-irradiated ITER-grade W retained 2.8 times more deuterium than pristine W, while TiB$_2$ showed the lowest D$_2$ release in the Ohmic set. VTaHfMo was the most stable refractory multi-principal-element alloy. NbC and (Nb$_{0.5}$Ta$_{0.5}$)C retained integrity with 0.02-0.03 mg mass loss, whereas ZrC lost 7 mg. CVD SiC retained macroscopic integrity but exhibited an effective Si erosion yield of 0.5, about 5-10 times above prior DIII-D trends. Renewable boron pebble rods underwent controlled recession; 13% of released boron was ionized near the outer strike point and up to 50% was recovered locally. Initial in-situ chromium gross-erosion measurements yielded values of order $10^{-2}$. Together, these results provide cross-material benchmarks for fusion pilot plant down-selection and future AI/ML-assisted plasma-facing-material development.