Quantum information processing (QIP) with solid state spin qubits strongly depends on the efficient initialisation of the qubit's desired charge state. While the negatively charged tin-vacancy (SnV−) centre in diamond has emerged as an excellent platform for realising QIP protocols due to long spin coherence times at liquid helium temperature and lifetime limited optical transitions, its usefulness is severely limited by termination of the fluorescence under resonant excitation [1,2,3]. Here, we unveil the underlying charge cycle of group IV-vacancy (G4V) centres and exploit it to demonstrate highly efficient initialisation of the desired negative charge state of single SnV centres while preserving long term stable optical resonances. We furthermore all-optically probe the coherence of the ground state spins by means of coherent population trapping and find a spin dephasing time of 5μs. Additionally, we demonstrate proof-of-principle single shot spin state readout without the necessity of a magnetic field aligned to the symmetry axis of the defect.
@article{arxiv.2110.05451,
title = {Coherence of a charge stabilised tin-vacancy spin in diamond},
author = {Johannes Görlitz and Dennis Herrmann and Philipp Fuchs and Takayuki Iwasaki and Takashi Taniguchi and Detlef Rogalla and David Hardeman and Pierre-Olivier Colard and Matthew Markham and Mutsuko Hatano and Christoph Becher},
journal= {arXiv preprint arXiv:2110.05451},
year = {2022}
}