Chiral Plasmonic Hydrogen Sensors
Abstract
In this article, a chiral plasmonic hydrogen-sensing platform using palladium-based nanohelices is demonstrated. Such 3D chiral nanostructures fabricated by nanoglancing angle deposition exhibit strong circular dichroism both experimentally and theoretically. The chiroptical properties of the palladium nanohelices are altered upon hydrogen uptake and sensitively depend on the hydrogen concentration. Such properties are well suited for remote and spark-free hydrogen sensing in the flammable range. Hysteresis is reduced, when an increasing amount of gold is utilized in the palladium-gold hybrid helices. As a result, the linearity of the circular dichroism in response to hydrogen is significantly improved. The chiral plasmonic sensor scheme is of potential interest for hydrogen-sensing applications, where good linearity and high sensitivity are required.
Cite
@article{arxiv.2105.00803,
title = {Chiral Plasmonic Hydrogen Sensors},
author = {Marcus Matuschek and Dhruv Pratap Singh and Hyeon-Ho Jeong and Maxim Nesterov and Thomas Weiss and Peer Fischer and Frank Neubrech and Na Liu},
journal= {arXiv preprint arXiv:2105.00803},
year = {2021}
}