English

Chiral phonons in sixfold chiral CrSi$_2$: Raman spectroscopy and first-principles calculations

Materials Science 2026-02-20 v1

Abstract

Chiral phonons have been identified in several chiral crystals, primarily in those with trigonal symmetry and threefold screw axes. In this study, chiral phonons in CrSi2_2, a chiral crystal with a sixfold helical structure, were investigated. Circularly polarized Raman spectroscopy revealed a subtle splitting of doubly degenerate E2E_2 phonon modes between cross-circular polarization configurations. These observations, supported by first-principles phonon calculations, indicate the presence of chiral phonons in CrSi2_2, expanding the scope of materials that exhibit chiral vibrational modes beyond the conventional trigonal class.

Keywords

Cite

@article{arxiv.2602.17362,
  title  = {Chiral phonons in sixfold chiral CrSi$_2$: Raman spectroscopy and first-principles calculations},
  author = {Gakuto Kusuno and Shingo Kisanuki and Yusuke Kousaka and Yoshihiko Togawa and Takuya Satoh},
  journal= {arXiv preprint arXiv:2602.17362},
  year   = {2026}
}

Comments

26 pages, 9 figures