Charm-Meson $t$-channel Singularities in an Expanding Hadron Gas

We study the time evolution of the numbers of charm mesons after the kinetic freezeout of the expanding hadron gas produced by the hadronization of the quark-gluon plasma from a central heavy-ion collision. The $\pi D$ reaction rates have contributions from a $D^\ast$ resonance in the $s$ channel. The $\pi D^\ast$ reaction rates are enhanced by $t$-channel singularities from an intermediate $D$. The contributions to reaction rates from $D^\ast$ resonances and $D$-meson $t$-channel singularities are sensitive to thermal mass shifts and thermal widths. In the expanding hadron gas, the $t$-channel singularities are regularized by the thermal $D$ widths. After kinetic freezeout, the thermal $D$ widths are dominated by coherent pion forward scattering. The contributions to $\pi D^\ast$ reaction rates from $t$-channel singularities are inversely proportional to the pion number density, which decreases to 0 as the hadron gas expands. The $t$-channel singularities produce small but significant changes in charm-meson ratios from those predicted using the known $D^\ast$-decay branching fractions.