English

Canted ferromagnetic order in a distorted triangular-lattice magnet Na$_2$SrCo(VO$_4$)$_2$

Strongly Correlated Electrons 2026-03-10 v1 Materials Science

Abstract

Triangular-lattice cobaltates with glaserite-type X2YX_2YCo(TTO4)2_4)_2 structure provide an ideal platform to investigate intriguing quantum magnetism. Here we report a comprehensive study of the structural and magnetic properties of a triangular-lattice cobalt vanadate Na2SrCo(VO4)2\rm Na_2SrCo(VO_4)_2. Room-temperature x-ray and neutron powder diffraction confirm that Na2SrCo(VO4)2\rm Na_2SrCo(VO_4)_2 crystallizes in the monoclinic P21/cP2_1/c space group with slightly distorted triangular layers of Co2+\rm Co^{2+} ions. Magnetization measurements reveal a ferromagnetic transition at TC3.4 KT\rm_C \approx 3.4~{\rm K}, where a sharp λ\lambda-type anomaly is observed in the specific heat. The magnetic entropy recovered up to 55 K approaches 90%\% of Rln2R{\rm ln}2, supporting an effective spin-1/2 state of Co2+^{2+} ions at low temperature. Neutron diffraction at 2.3 K (below TCT_{\rm C}) further confirms a long-range canted ferromagnetic order with the Co2+^{2+} moments aligned in the acac plane and the ordered moment size of \sim 2.6 μB\mu\rm_{B}. Comparing with its sister compounds with a trigonal symmetry, Na2BaCo(VO4)2\rm Na_2BaCo(VO_4)_2 with a collinear ferromagnetic structure and the recently discovered spin supersolid candidate Na2BaCo(PO4)2\rm Na_2BaCo(PO_4)_2 with a distinct Y-like antiferromagnetic ground state, this study indicates the decisive role of the TO4T{\rm O_4} tetrahedra in tuning exchange interactions and contrasting magnetic behaviors of these glaserite-structure compounds.

Keywords

Cite

@article{arxiv.2512.15090,
  title  = {Canted ferromagnetic order in a distorted triangular-lattice magnet Na$_2$SrCo(VO$_4$)$_2$},
  author = {Tengfei Peng and Xiaobai Ma and Xinyang Liu and Feiran Shen and Lunhua He and Junsen Xiang and Wenyun Yang and Wentao Jin},
  journal= {arXiv preprint arXiv:2512.15090},
  year   = {2026}
}

Comments

10 pages, 6 figures