Brownian non-Gaussian polymer diffusion and queing theory in the mean-field limit
Abstract
We link the Brownian non-Gaussian diffusion of a polymer center of mass to a microscopic cause: the polymerization/depolymerization phenomenon occurring when the polymer is in contact with a monomer chemostat. The anomalous behavior is triggered by the polymer critical point, separating the dilute and the dense phase in the grand canonical ensemble. In the mean-field limit we establish contact with queuing theory and show that the kurtosis of the polymer center of mass diverges alike a response function when the system becomes critical, a result which holds for general polymer dynamics (Zimm, Rouse, reptation). Both the equilibrium and nonequilibrium behaviors are solved exactly as a reference study for novel stochastic modeling and experimental setup.
Keywords
Cite
@article{arxiv.2202.01605,
title = {Brownian non-Gaussian polymer diffusion and queing theory in the mean-field limit},
author = {Sankaran Nampoothiri and Enzo Orlandini and Flavio Seno and Fulvio Baldovin},
journal= {arXiv preprint arXiv:2202.01605},
year = {2022}
}
Comments
18 pages, 7 figures