Boundary and impurity effects on entanglement of Heisenberg chains

We study entanglement of a pair of qubits and the bipartite entanglement between the pair and the rest within open-ended Heisenberg $XXX$ and XY models. The open boundary condition leads to strong oscillations of entanglements with a two-site period, and the two kinds of entanglements are 180 degree out of phase with each other. The mean pairwise entanglement and ground-state energy per site in the $XXX$ model are found to be proportional to each other. We study the effects of a single bulk impurity on entanglement, and find that there exists threshold values of the relative coupling strength between the impurity and its nearest neighbours, after which the impurity becomes pairwise entangled with its nearest neighbours.