The study of open-shell nanographenes has relied on a paradigm where spins are the only low-energy degrees of freedom. Here we show that some nanographenes can host low-energy excitations that include strongly coupled spin and orbital degrees of freedom. The key ingredient is the existence of orbital degeneracy, as a consequence of leaving the benzenoid/half-filling scenario. We analyze the case of nitrogen-doped triangulenes, using both density-functional theory and Hubbard model multiconfigurational and random-phase approximation calculations. We find a rich interplay between orbital and spin degrees of freedom that confirms the need to go beyond the spin-only paradigm, opening a new venue in this field of research.
@article{arxiv.2312.04938,
title = {Beyond spin models in orbitally-degenerate open-shell nanographenes},
author = {J. C. G. Henriques and D. Jacob and A. Molina-Sánchez and G. Catarina and A. T. Costa and J. Fernández-Rossier},
journal= {arXiv preprint arXiv:2312.04938},
year = {2023}
}