Battery Detached Energy Conversion by Pyroelectric Effect

We propose a pyroelectric energy conversion device that converts heat directly to electricity. In contrast to conventional pyroelectric energy conversion designs, this energy harvesting system is detached from any external power sources, operating only under periodically varying temperature. Such detachment unambiguously attributes the converted electricity to heat that drives the change of polarization in the pyroelectric material, not to the electric field alternation caused by the external battery. Using pure and Zr doped BaTiO$_3$, we demonstrate the electricity generation in consecutive temperature cycles. We further develop a thermodynamic model for the energy conversion system. Our model suggests that the work output is rate dependent: the work output per cycle is linearly dependent on the heat/cooling frequency below the predicted threshold. The linearity is confirmed by experiments, and the threshold frequency is derived by theory. Finally we propose a figure of merit that separates the materials intrinsic properties from the system design parameters. The figure of merit guides the future material development and device improvement. Our work clears out confusions and reforms the foundation for pyroelectric materials' resurgence as a competitor for green electricity.