English

Barrierless Electronic Relaxation in Solution: An analytically solvable model with arbitrary coupling

Chemical Physics 2013-08-08 v2

Abstract

In our recent publication, we have proposed an analytical method for solving the problem of electronic relaxation in solution, modeled by a particle undergoing diffusive motion under the influence of two arbitrary potentials and the coupling between the two potentials was assumed to be localized at one point. In this paper we have extended our work to deal with the case of delocalized coupling between two potentials. The average and long term rate constant for delocalized coupling is presented.

Keywords

Cite

@article{arxiv.1308.1354,
  title  = {Barrierless Electronic Relaxation in Solution: An analytically solvable model with arbitrary coupling},
  author = {Aniruddha Chakraborty},
  journal= {arXiv preprint arXiv:1308.1354},
  year   = {2013}
}

Comments

arXiv admin note: substantial text overlap with arXiv:1308.0659

R2 v1 2026-06-22T01:04:55.244Z