The hydrogen atom under the pressure of a spherical penetrable confinement potential of a decreasing radius r0 is explored, as a case study. A novel counter-intuitive effect of atomic swelling rather than shrinking with decreasing r0 is unraveled, when r0 reaches, and remains smaller than, a certain critical value. Upon swelling, the size of the atom is shown to increase by an order of magnitude, or more, compared to the size of the free atom. Examples of changes of photoabsorption properties of confined hydrogen atom upon its swelling are uncovered and demonstrated.
@article{arxiv.1208.3768,
title = {Atomic swelling upon compression},
author = {V. K. Dolmatov and J. L. King},
journal= {arXiv preprint arXiv:1208.3768},
year = {2015}
}