English

Asymptotic properties of bridging transitions in sinusoidally-shaped slits

Soft Condensed Matter 2024-11-19 v1 Mesoscale and Nanoscale Physics Statistical Mechanics

Abstract

We study bridging transitions that emerge between two sinusoidally-shaped walls of amplitude AA, wavenumber kk, and mean separation LL. The focus is on weakly corrugated walls to examine the properties of bridging transitions in the limit when the walls become flat. The reduction of walls roughness can be achieved in two ways which we show differ qualitatively: a) By decreasing kk, (i.e., by increasing the system wavelength), which induces a continuous phenomenon associated with the growth of bridging films concentrated near the system necks, the thickness of with the thickness of these films diverging as k2/3\sim k^{-2/3} in the limit of k0k\to0. Simultaneously, the location of the transition approaches that of capillary condensation in an infinite planar slit of an appropriate width as k2/3\sim k^{2/3}; b) in contrast, the limit of vanishing walls roughness by reducing AA cannot be considered in this context, as there exists a minimal value Amin(k,L)A_{\rm min}(k,L) of the amplitude below which bridging transition does not occur. On the other hand, for amplitudes A>Amin(k,L)A>A_{\rm min}(k,L), the bridging transition always precedes global condensation in the system. These predictions, including the scaling property AminkL2A_{\rm min}\propto kL^2, are verified numerically using density functional theory.

Keywords

Cite

@article{arxiv.2411.11509,
  title  = {Asymptotic properties of bridging transitions in sinusoidally-shaped slits},
  author = {Alexandr Malijevský and Martin Pospíšil},
  journal= {arXiv preprint arXiv:2411.11509},
  year   = {2024}
}

Comments

10 pages, 6 figures, Physical Review E (accepted)