English

Asphaltene aggregation onset during high-salinity waterflooding of reservoirs (a molecular dynamic study)

Chemical Physics 2019-07-02 v2 Soft Condensed Matter

Abstract

The primary objective of this study is to establish an understanding of the role of high-salinity brine on the intensity of asphaltene aggregation onset during waterflooding of petroleum reservoirs. We already have shown that asphaltenes have a high tendency to form aggregates during waterflooding process when pure- and low salinity-water are injected into reservoirs. To fulfill the present objective, molecular dynamic simulations are performed on asphaltenic-oil/aqueous systems. The oil phase consists of asphaltenes and ortho-xylene, in which asphaltene molecules are completely soluble. Our simulations results reveal that the salt-in effect of high-salinity brine on seven different model asphaltenic oils causes a significant reduction of the onset of asphaltene aggregation as compared with pure-water. Such salt-in effect is primarily due to a considerable reduction of water miscibility in the oil phase at high pressure and temperature.

Keywords

Cite

@article{arxiv.1906.08114,
  title  = {Asphaltene aggregation onset during high-salinity waterflooding of reservoirs (a molecular dynamic study)},
  author = {Salah Yaseen and G. Ali Mansoori},
  journal= {arXiv preprint arXiv:1906.08114},
  year   = {2019}
}