English

Arrangement and chemical complexity in an $N$-body quantum system

Quantum Physics 2022-11-18 v1 Atomic Physics Chemical Physics

Abstract

We introduce and discuss the concept of \textit{arrangement}, traditionally found in the context of chemical reactions and few-body rearrangement collisions, in the general context of an NN-body quantum system. We show that the ability for particles to attract and bind is a key source of complexity of an NN-body quantum system, and \textit{arrangement} is an emergent concept necessitated by the description of this complexity. For an NN-body system made of particles of which some or all can attract and bind, the concept of arrangement is not only necessary for a full characterization of its quantum states and processes, but it also provides a basis for the understanding and the description of the structure of its energy spectrum. We also discuss and formulate multiparticle separability in an NN-body system, the mathematical foundation that underlies the arrangement concept in an NN-body theory.

Keywords

Cite

@article{arxiv.2211.09318,
  title  = {Arrangement and chemical complexity in an $N$-body quantum system},
  author = {Bo Gao},
  journal= {arXiv preprint arXiv:2211.09318},
  year   = {2022}
}

Comments

9 pages, 2 figures