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Antiferromagnetic ordering and glassy nature in NASICON type NaFe$_2$PO$_4$(SO$_4$)$_2$

Strongly Correlated Electrons 2024-03-14 v1 Materials Science

Abstract

We investigate crystal structure and magnetic properties including spin relaxation and magnetocaloric effect in NASICON type NaFe2_2PO4_4(SO4_4)2_2 sample. The Rietveld refinement of x-ray and neutron diffraction patterns show a rhombohedral crystal structure with the R3ˉ\bar{3}c space group. The core-level spectra confirm the desired oxidation state of constituent elements. The {\it dc}--magnetic susceptibility (χ\chi) behavior in zero field-cooled (ZFC) and field-cooled (FC) modes show the ordering temperature \approx50~K. Interestingly, the analysis of temperature dependent neutron diffraction patterns reveal an A-type antiferromagnetic (AFM) structure with the ordered moment of 3.8 μB\mu_{B}/Fe3+^{3+} at 5~K, and a magnetostriction below TN=T_{\rm N}= 50~K. Further, the peak position in the {\it ac}--χ\chi is found to be invariant with the excitation frequency supporting the notion of dominating AFM transition. Also, the unsaturated isothermal magnetization curve supports the AFM ordering of the moments; however, the observed coercivity suggests the presence of weak ferromagnetic (FM) correlations at 5~K. On the other hand, a clear bifurcation between ZFC and FC curves of {\it dc}--χ\chi and the observed decrease in peak height of {\it ac}--χ\chi with frequency suggest for the complex magnetic interactions. The spin relaxation behavior in thermo-remanent magnetization and aging measurements indicate the glassy states at 5~K. Moreover, the Arrott plots and magnetocaloric analysis reveal the AFM--FM interactions in the sample at lower temperatures.

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Cite

@article{arxiv.2403.08679,
  title  = {Antiferromagnetic ordering and glassy nature in NASICON type NaFe$_2$PO$_4$(SO$_4$)$_2$},
  author = {Manish Kr. Singh and A. K. Bera and Ajay Kumar and S. M. Yusuf and R. S. Dhaka},
  journal= {arXiv preprint arXiv:2403.08679},
  year   = {2024}
}

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