We investigate crystal structure and magnetic properties including spin relaxation and magnetocaloric effect in NASICON type NaFe2PO4(SO4)2 sample. The Rietveld refinement of x-ray and neutron diffraction patterns show a rhombohedral crystal structure with the R3ˉc space group. The core-level spectra confirm the desired oxidation state of constituent elements. The {\it dc}--magnetic susceptibility (χ) behavior in zero field-cooled (ZFC) and field-cooled (FC) modes show the ordering temperature ≈50~K. Interestingly, the analysis of temperature dependent neutron diffraction patterns reveal an A-type antiferromagnetic (AFM) structure with the ordered moment of 3.8 μB/Fe3+ at 5~K, and a magnetostriction below TN= 50~K. Further, the peak position in the {\it ac}--χ is found to be invariant with the excitation frequency supporting the notion of dominating AFM transition. Also, the unsaturated isothermal magnetization curve supports the AFM ordering of the moments; however, the observed coercivity suggests the presence of weak ferromagnetic (FM) correlations at 5~K. On the other hand, a clear bifurcation between ZFC and FC curves of {\it dc}--χ and the observed decrease in peak height of {\it ac}--χ with frequency suggest for the complex magnetic interactions. The spin relaxation behavior in thermo-remanent magnetization and aging measurements indicate the glassy states at 5~K. Moreover, the Arrott plots and magnetocaloric analysis reveal the AFM--FM interactions in the sample at lower temperatures.
@article{arxiv.2403.08679,
title = {Antiferromagnetic ordering and glassy nature in NASICON type NaFe$_2$PO$_4$(SO$_4$)$_2$},
author = {Manish Kr. Singh and A. K. Bera and Ajay Kumar and S. M. Yusuf and R. S. Dhaka},
journal= {arXiv preprint arXiv:2403.08679},
year = {2024}
}