English

Antiferromagnetic Exchange Interaction between Electrons on Degenerate LUMOs in Benzene Dianion

Strongly Correlated Electrons 2015-06-11 v1 Materials Science Atomic and Molecular Clusters

Abstract

We discuss the ground state of Benzene dianion (Bz2^{2-}) on the basis of the numerical diagonalization method of an effective model of π\pi orbitals. It is found that the ground state can be the spin singlet state, and the exchange coupling between LUMOs can be antiferromagnetic.

Keywords

Cite

@article{arxiv.1208.2817,
  title  = {Antiferromagnetic Exchange Interaction between Electrons on Degenerate LUMOs in Benzene Dianion},
  author = {Hiroyasu Matsuura and Kazumasa Miyake and Hidetoshi Fukuyama},
  journal= {arXiv preprint arXiv:1208.2817},
  year   = {2015}
}

Comments

Accepted for publication in J. Phys. Soc. Jpn., 2 pages, 3 figures