Anomalous isotopic effect on electron-directed reactivity by a 3-{\mu}m midinfrared pulse
Abstract
We have theoretically studied the effect of nuclear mass on electron localization in dissociating H_2^+ and its isotopes subjected to a few-cycle 3-{\mu}m laser pulse. Compared to the isotopic trend in the near-infrared regime, our results reveal an inverse isotopic effect in which the degree of electron-directed reactivity is even higher for heavier isotopes. With the semi-classical analysis, we find, for the first time, the pronounced electron localization is established by the interferences through different channels of one- and, more importantly, higher-order photon coupling. Interestingly, due to the enhanced high-order above-threshold dissociation of heavier isotopes, the interference maxima gradually become in phase with growing mass and ultimately lead to the anomalous isotopic behavior of the electron localization. This indicates that the multi-photon coupling channels will play an important role in controlling the dissociation of larger molecules with midinfrared pulses.
Keywords
Cite
@article{arxiv.1211.1135,
title = {Anomalous isotopic effect on electron-directed reactivity by a 3-{\mu}m midinfrared pulse},
author = {Kunlong Liu and Qingbin Zhang and Pengfei Lan and Peixiang Lu},
journal= {arXiv preprint arXiv:1211.1135},
year = {2015}
}
Comments
5 pages, 4 figures