English

Analytic evaluation of some three- and four- electron atomic integrals involving s STO's and exponential correlation with unlinked $r_{ij}$'s

Atomic Physics 2017-01-23 v1

Abstract

The method of evaluation outlined in a previous work has been utilized here to evaluate certain other three- electron and four- electron atomic integrals involving s Slater-type orbitals and exponential correlation with unlinked rijr_{ij}'s. Limiting expressions for various such integrals have been derived, which has not been done earlier. Closed-form expressions for <r12r13/r14><r_{12} r_{13} / r_{14}>, <r12r34/r23><r_{12}r_{34}/r_{23}>, <r12r23/r34><r_{12}r_{23}/r_{34}>, <r12r13/r34><r_{12}r_{13}/r_{34}> and <r12r34/r13><r_{12}r_{34}/r_{13}> have been obtained.

Keywords

Cite

@article{arxiv.1701.05701,
  title  = {Analytic evaluation of some three- and four- electron atomic integrals involving s STO's and exponential correlation with unlinked $r_{ij}$'s},
  author = {B Padhy},
  journal= {arXiv preprint arXiv:1701.05701},
  year   = {2017}
}

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35 pages