English

Analysis of some heterogeneous catalysis models with fast sorption and fast surface chemistry

Analysis of PDEs 2021-05-10 v1 Functional Analysis

Abstract

We investigate limit models resulting from a dimensional analysis of quite general heterogeneous catalysis models with fast sorption (i.e.\ exchange of mass between the bulk phase and the catalytic surface of a reactor) and fast surface chemistry for a prototypical chemical reactor. For the resulting reaction-diffusion systems with linear boundary conditions on the normal mass fluxes, but at the same time nonlinear boundary conditions on the concentrations itself, we provide analytic properties such as local-in time well-posedness, positivity and global existence of strong solutions in the class Wp(1,2)(J×Ω;RN)\mathrm{W}^{(1,2)}_p(J \times \Omega; \mathbb{R}^N), and of classical H\"older solutions in the class C(1+α,2+2α)(J×Ω)\mathrm{C}^{(1+\alpha, 2 + 2\alpha)}(\overline J \times \overline{\Omega}). Exploiting that the model is based on thermodynamic principles, we further show a priori bounds related to mass conservation and the entropy principle.

Keywords

Cite

@article{arxiv.2006.12098,
  title  = {Analysis of some heterogeneous catalysis models with fast sorption and fast surface chemistry},
  author = {Björn Augner and Dieter Bothe},
  journal= {arXiv preprint arXiv:2006.12098},
  year   = {2021}
}

Comments

29 pages, published in Journal of Evolution Equations (2021)