English

Analysis and optimization of weighted ensemble sampling

Numerical Analysis 2018-10-17 v3 Chemical Physics

Abstract

We give a mathematical framework for weighted ensemble (WE) sampling, a binning and resampling technique for efficiently computing probabilities in molecular dynamics. We prove that WE sampling is unbiased in a very general setting that includes adaptive binning. We show that when WE is used for stationary calculations in tandem with a coarse model, the coarse model can be used to optimize the allocation of replicas in the bins.

Keywords

Cite

@article{arxiv.1609.05887,
  title  = {Analysis and optimization of weighted ensemble sampling},
  author = {David Aristoff},
  journal= {arXiv preprint arXiv:1609.05887},
  year   = {2018}
}

Comments

22 pages, 3 figures

R2 v1 2026-06-22T15:54:36.934Z