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An ab initio non-equilibrium Green's function approach to charge transport: dithiolethine

Materials Science 2007-05-23 v1 Strongly Correlated Electrons

Abstract

We present a novel ab initio non-equilibrium approach to calculate the current across a molecular junction. The method rests on a wave function based full ab initio description of the central region of the junction combined with a tight binding approximation for the electrodes in the frame of the Keldysh Green's function formalism. Our procedure is demonstrated for a dithiolethine molecule between silver electrodes. The main conducting channel is identified and the full current-voltage characteristic is calculated.

Keywords

Cite

@article{arxiv.cond-mat/0510211,
  title  = {An ab initio non-equilibrium Green's function approach to charge transport: dithiolethine},
  author = {Alexander Schnurpfeil and Bo Song and Martin Albrecht},
  journal= {arXiv preprint arXiv:cond-mat/0510211},
  year   = {2007}
}

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