English

Active crystallization from power functional theory

Soft Condensed Matter 2024-02-28 v2 Statistical Mechanics

Abstract

We address the gas, liquid, and crystal phase behaviour of active Brownian particles in three dimensions. The nonequilibrium force balance at coexistence leads to equality of state functions for which we use power functional approximations. Motility-induced phase separation starts at a critical point and quickly becomes metastable against active freezing for P\'eclet numbers above a nonequilibrium triple point. The mean swim speed acts as a state variable, similar to the density of depletion agents in colloidal demixing. We obtain agreement with recent simulation results and correctly predict the strength of particle number fluctuations in active fluids.

Keywords

Cite

@article{arxiv.2308.10614,
  title  = {Active crystallization from power functional theory},
  author = {Sophie Hermann and Matthias Schmidt},
  journal= {arXiv preprint arXiv:2308.10614},
  year   = {2024}
}

Comments

7 pages, 2 figures

R2 v1 2026-06-28T12:00:17.731Z