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Accurate measurement of ^{13}C - ^{15}N distances with solid-state NMR

Other Condensed Matter 2007-05-23 v1

Abstract

Solid-state NMR technique for measureing distances between hetero-nuclei in static powder samples is described. It is based on a two-dimensional single-echo scheme enhanced with adiabatic cross-polarization. As an example, the results for intra-molecular distances in α\alpha-crystalline form of glycine are presented. The measured NMR distances ^13 C(2) - ^15 N and ^13 C(1) - ^15 N are 1.496 ±\pm 0.002 \AA and 2.50 ±\pm 0.02 \AA, respectively.

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Cite

@article{arxiv.cond-mat/0602439,
  title  = {Accurate measurement of ^{13}C - ^{15}N distances with solid-state NMR},
  author = {Jae-Seung Lee and A. K. Khitrin},
  journal= {arXiv preprint arXiv:cond-mat/0602439},
  year   = {2007}
}

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12 pages