English

Abundance of unknots in various models of polymer loops

Statistical Mechanics 2009-11-11 v1 Soft Condensed Matter

Abstract

A veritable zoo of different knots is seen in the ensemble of looped polymer chains, whether created computationally or observed in vitro. At short loop lengths, the spectrum of knots is dominated by the trivial knot (unknot). The fractional abundance of this topological state in the ensemble of all conformations of the loop of NN segments follows a decaying exponential form, exp(N/N0) \sim \exp (-N/N_0), where N0N_0 marks the crossover from a mostly unknotted (ie topologically simple) to a mostly knotted (ie topologically complex) ensemble. In the present work we use computational simulation to look closer into the variation of N0N_0 for a variety of polymer models. Among models examined, N0N_0 is smallest (about 240) for the model with all segments of the same length, it is somewhat larger (305) for Gaussian distributed segments, and can be very large (up to many thousands) when the segment length distribution has a fat power law tail.

Keywords

Cite

@article{arxiv.cond-mat/0604225,
  title  = {Abundance of unknots in various models of polymer loops},
  author = {N. T. Moore and A. Y. Grosberg},
  journal= {arXiv preprint arXiv:cond-mat/0604225},
  year   = {2009}
}

Comments

13 pages, 6 color figures