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Absorbing Boundary Conditions for Time-dependent Schr\"{o}dinger equations: A Density-matrix Formulation

Numerical Analysis 2019-05-01 v1

Abstract

This paper presents some absorbing boundary conditions (ABC) for simulations based on the time-dependent density-functional theory (TDDFT). The boundary conditions are expressed in terms of the elements of the density-matrix, and it is derived from the full model over a much larger domain. To make the implementation much more efficient, several approximations for the convolution integral will be constructed with guaranteed stability. These approximations lead to modified density-matrix equations at the boundary. The effectiveness is examined via numerical tests.

Keywords

Cite

@article{arxiv.1811.00579,
  title  = {Absorbing Boundary Conditions for Time-dependent Schr\"{o}dinger equations: A Density-matrix Formulation},
  author = {Xiantao Li},
  journal= {arXiv preprint arXiv:1811.00579},
  year   = {2019}
}