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A Velocity Map Imaging apparatus optimized for high-resolution crossed molecular beam experiments

Atomic Physics 2021-11-09 v1 Chemical Physics

Abstract

We present the design of a Velocity Map Imaging apparatus tailored to the demands of high-resolution crossed molecular beam experiments employing Stark or Zeeman decelerators. The key requirements for these experiments consist of the combination of a high relative velocity resolution for large ionization volumes and a broad range of relatively low lab-frame velocities. The SIMION software package was employed to systematically optimize the electrode geometries and electrical configuration. The final design consists of a stack of 16 tubular electrodes, electrically connected with resistors, which is divided into three electric field regions. The resulting apparatus allows for an inherent velocity blurring of less than 1.1 m/s for NO+^+ ions originating from a 3x3x3 mm ionization volume, which is negligible in a typical crossed beam experiment. The design was recently employed in several state of the art crossed-beam experiments, allowing the observation of fine details in the velocity distributions of the scattered molecules.

Keywords

Cite

@article{arxiv.2007.04852,
  title  = {A Velocity Map Imaging apparatus optimized for high-resolution crossed molecular beam experiments},
  author = {Vikram Plomp and Zhi Gao and Sebastiaan Y. T. van de Meerakker},
  journal= {arXiv preprint arXiv:2007.04852},
  year   = {2021}
}
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