A Solution to the Combinatorial Puzzle of Mayer's Virial Expansion
Mathematical Physics
2015-10-08 v4 Combinatorics
math.MP
Abstract
Mayer's second theorem in the context of a classical gas model allows us to write the coefficients of the virial expansion of pressure in terms of weighted two-connected graphs. Labelle, Leroux and Ducharme studied the graph weights arising from the one-dimensional hardcore gas model and noticed that the sum of these weights over all two-connected graphs with vertices is . This paper addresses the question of achieving a purely combinatorial proof of this observation.
Keywords
Cite
@article{arxiv.1402.2119,
title = {A Solution to the Combinatorial Puzzle of Mayer's Virial Expansion},
author = {Stephen James Tate},
journal= {arXiv preprint arXiv:1402.2119},
year = {2015}
}
Comments
25 pages, 6 figures