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A Solution to the Combinatorial Puzzle of Mayer's Virial Expansion

Mathematical Physics 2015-10-08 v4 Combinatorics math.MP

Abstract

Mayer's second theorem in the context of a classical gas model allows us to write the coefficients of the virial expansion of pressure in terms of weighted two-connected graphs. Labelle, Leroux and Ducharme studied the graph weights arising from the one-dimensional hardcore gas model and noticed that the sum of these weights over all two-connected graphs with nn vertices is n(n2)!-n(n-2)!. This paper addresses the question of achieving a purely combinatorial proof of this observation.

Keywords

Cite

@article{arxiv.1402.2119,
  title  = {A Solution to the Combinatorial Puzzle of Mayer's Virial Expansion},
  author = {Stephen James Tate},
  journal= {arXiv preprint arXiv:1402.2119},
  year   = {2015}
}

Comments

25 pages, 6 figures