A New Approach to Analyse $H\otimes (2h\oplus g)$ Jahn-Teller System for $C_{60}$
Chemical Physics
2009-11-11 v1 Quantum Physics
Abstract
It is now well known that electron (hole)-vibron coupling and hence Jahn-Teller (JT) effect is important understanding the properties of and related molecules. In this paper, we study coupling case to find the potential energy surfaces for the positively charged molecule due to distortion. The Jahn-Teller system is of particular importance as this will be the JT effect displayed by molecules removed with an electron. is obtained by removing one electron from fivefold degenerate Hu highest occupied molecular orbital (HOMO) and a hole in HOMO interacts with the vibrational modes of and symmetry is broken. We apply the method of symmetry breaking mechanism to obtain expressions for the potential energy surface.
Keywords
Cite
@article{arxiv.physics/0511125,
title = {A New Approach to Analyse $H\otimes (2h\oplus g)$ Jahn-Teller System for $C_{60}$},
author = {Ramazan Koc and Hayriye Tutunculer and Mehmet Koca},
journal= {arXiv preprint arXiv:physics/0511125},
year = {2009}
}