English

A minimal model for kinetic arrest

Statistical Mechanics 2009-11-13 v1 Soft Condensed Matter

Abstract

To elucidate slow dynamics in glassy materials, we introduce the {\it Figure-8 model} in which NN hard blocks undergo Brownian motion around a circuit in the shape of a figure-8. This system undergoes kinetic arrest at a critical packing fraction ϕ=ϕg<1\phi=\phi_g < 1, and for ϕϕg\phi\approx\phi_g long-time diffusion is controlled by rare, cooperative `junction-crossing' particle rearrangements. We find that the average time between junction crossings τJC\tau_{JC}, and hence the structural relaxation time, does not simply scale with the configurational volume \OmegaLow\OmegaLow of transition states, because τJC\tau_{JC} also depends on the time to complete a junction crossing. The importance of these results in understanding cage-breaking dynamics in glassy systems is discussed.

Keywords

Cite

@article{arxiv.0804.2060,
  title  = {A minimal model for kinetic arrest},
  author = {Prasanta Pal and Corey S. O'Hern and Jerzy Blawzdziewicz and Robin Stinchcombe},
  journal= {arXiv preprint arXiv:0804.2060},
  year   = {2009}
}

Comments

4 pages, 4 figures

R2 v1 2026-06-21T10:30:18.489Z