A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

Farida H. Aidoudi; Lewis J. Downie; Russell E. Morris; Mark de Vries; Philip Lightfoot

doi:10.1039/c4dt00452c

A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

Strongly Correlated Electrons 2014-04-08 v1

Authors: Farida H. Aidoudi , Lewis J. Downie , Russell E. Morris , Mark de Vries , Philip Lightfoot

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Abstract

A new organically-templated vanadium (III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling within the ground state a pronounced change in magnetisation kinetics is observed.

Keywords

kagome lattice

Cite

@article{arxiv.1404.1755,
  title  = {A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers},
  author = {Farida H. Aidoudi and Lewis J. Downie and Russell E. Morris and Mark de Vries and Philip Lightfoot},
  journal= {arXiv preprint arXiv:1404.1755},
  year   = {2014}
}

Comments

14 pages, 13 figures

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