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A generating integral for the matrix elements of the Coulomb Green's function with the Coulomb wave functions

Quantum Physics 2020-03-18 v3 Mathematical Physics math.MP

Abstract

We analytically evaluate the generating integral Knl(β,β)=00eβrβrGnlrqrqdrdrK_{nl}(\beta,\beta') = \int_{0}^{\infty}\int_{0}^{\infty} e^{-\beta r - \beta' r'}G_{nl} r^{q} r'^{q'} dr dr' and integral moments Jnl(β,r)=0drGnl(r,r)rqeβrJ_{nl}(\beta, r) = \int_{0}^{\infty} dr' G_{nl}(r,r') r'^{q} e^{-\beta r'} for the reduced Coulomb Green's function Gnl(r,r)G_{nl}(r,r') for all values of the parameters qq and qq', when the integrals are convergent. These results can be used in second-order perturbation theory to analytically obtain the complete energy spectra and local physical characteristics such as electronic densities of multi-electron atoms or ions.

Keywords

Cite

@article{arxiv.1906.05144,
  title  = {A generating integral for the matrix elements of the Coulomb Green's function with the Coulomb wave functions},
  author = {K. Dzikowski and O. D. Skoromnik},
  journal= {arXiv preprint arXiv:1906.05144},
  year   = {2020}
}

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23 pages