English

A generalization of Onsager's reciprocity relations to gradient flows with nonlinear mobility

Statistical Mechanics 2018-10-16 v2 Dynamical Systems Probability Chemical Physics

Abstract

Onsager's 1931 `reciprocity relations' result connects microscopic time-reversibility with a symmetry property of corresponding macroscopic evolution equations. Among the many consequences is a variational characterization of the macroscopic evolution equation as a gradient-flow, steepest-ascent, or maximal-entropy-production equation. Onsager's original theorem is limited to close-to-equilibrium situations, with a Gaussian invariant measure and a linear macroscopic evolution. In this paper we generalize this result beyond these limitations, and show how the microscopic time-reversibility leads to natural generalized symmetry conditions, which take the form of generalized gradient flows.

Keywords

Cite

@article{arxiv.1510.06219,
  title  = {A generalization of Onsager's reciprocity relations to gradient flows with nonlinear mobility},
  author = {A. Mielke and M. A. Peletier and D. R. M. Renger},
  journal= {arXiv preprint arXiv:1510.06219},
  year   = {2018}
}

Comments

8 pages; contribution to the proceedings of IWNET 2015; this is the author version after taking into account reviewer's comments