English

A general comparison theorem

Quantum Physics 2011-02-18 v2

Abstract

Using the Hellmann-Feynman theorem, a general comparison theorem is established for an eigenvalue equation of the form (T+V)ψ>=Eψ>(T+V)|\psi> = E|\psi>, where TT is a kinetic part which depends only on momentums and VV is a potential which depends only on positions. We assume that H(1)=T+V(1)H^{(1)}=T+V^{(1)} and H(2)=T+V(2)H^{(2)}=T+V^{(2)} (H(1)=T(1)+VH^{(1)}=T^{(1)}+V and H(2)=T(2)+VH^{(2)}=T^{(2)}+V) support both discrete eigenvalues E{α}(1)E^{(1)}_{\{\alpha\}} and E{α}(2)E^{(2)}_{\{\alpha\}}, where {α}{\{\alpha\}} represents a set of quantum numbers. We prove that, if V(1)V(2)V^{(1)} \le V^{(2)} (T(1)T(2)T^{(1)} \le T^{(2)}) for all position (momentum) variables, then the corresponding eigenvalues are ordered E{α}(1)E{α}(2)E^{(1)}_{\{\alpha\}} \le E^{(2)}_{\{\alpha\}}. Some analytical applications are given.

Cite

@article{arxiv.1012.5355,
  title  = {A general comparison theorem},
  author = {Claude Semay},
  journal= {arXiv preprint arXiv:1012.5355},
  year   = {2011}
}

Comments

Presentation improved, results unchanged. Version to appear in Phys. Rev. A

R2 v1 2026-06-21T17:03:55.222Z