English

A Finite-field Approach for $GW$ Calculations Beyond the Random Phase Approximation

Chemical Physics 2018-12-19 v2 Materials Science Computational Physics

Abstract

We describe a finite-field approach to compute density response functions, which allows for efficient G0W0G_0W_0 and G0W0Γ0G_0W_0\Gamma_0 calculations beyond the random phase approximation. The method is easily applicable to density functional calculations performed with hybrid functionals. We present results for the electronic properties of molecules and solids and we discuss a general scheme to overcome slow convergence of quasiparticle energies obtained from G0W0Γ0G_0W_0\Gamma_0 calculations, as a function of the basis set used to represent the dielectric matrix.

Keywords

Cite

@article{arxiv.1808.10001,
  title  = {A Finite-field Approach for $GW$ Calculations Beyond the Random Phase Approximation},
  author = {He Ma and Marco Govoni and Francois Gygi and Giulia Galli},
  journal= {arXiv preprint arXiv:1808.10001},
  year   = {2018}
}
R2 v1 2026-06-23T03:48:26.530Z