English

A description of the Thomas-Fermi ion with fast converging function series

Quantum Physics 2014-02-11 v2

Abstract

This article concerns the description of the electron sea of an atomic ion with the Thomas-Fermi model. The normalized ion radius XX, ionization potential bb and electronic binding energy BB of the Thomas-Fermi ion are functions of the ratio NN of electrons to protons in the ion. A scheme is given to calculate the Taylor series of X(N)X(N), b(N)b(N) and B(N)B(N). With this scheme, the Taylor coefficients are calculated up to 5th order. The obtained 0th to 3rd order coefficients agree with the values presently available in the literature. To the authors knowledge, the 4th and 5th order coefficients are new results. It is then argued that a different series description of these functions, based on the Taylor series of c(N)b1/3X4/3c(N) \equiv b^{-1/3}X^{-4/3}, leads to a significant improvement in convergence.

Keywords

Cite

@article{arxiv.1309.6498,
  title  = {A description of the Thomas-Fermi ion with fast converging function series},
  author = {Herbert E. Müller},
  journal= {arXiv preprint arXiv:1309.6498},
  year   = {2014}
}

Comments

23 pages, 11 figures